Selective Ether Cleavage Synthesis of Liquid Crystals

Abstract

A method for making platform molecules comprising: reacting 4-alkoxy benzoyl chloride with R.sup.2-hydroquinone under first conditions effective to produce bis 1,4[4-alkoxy-benzoyloxy]-R.sup.2-phenylene comprising bis terminal alkoxy groups wherein R.sup.2 is a bulky organic group; and, subjecting the bis 1,4[4-alkoxy-benzoyloxy]-R.sup.2-phenylene to second conditions effective to selectively cleave the bis terminal alkoxy groups to produce a solution comprising complexes comprising diphenolic platform molecules comprising bis terminal hydroxyl groups, the second conditions also being effective to precipitate the complexes out of the solution.

Patent Number
7,147,800
Date Of Issue
Inventors

Stephen T. Wellinghoff, Douglas P. Hanson